That is explained by Ivan Ristic (Red Sift).

From the blogpost:
“Post-quantum signature sizes are up to 34x larger than ECDSA. Here’s why ML-DSA certificate chains blow past the 14.5 KB TCP congestion window. […]

In the following table, we compare the key aspects of ML-DSA to those of traditional cryptography. We show values for the common algorithms and strengths we normally see in leaf certificates and intermediates, which use stronger cryptography. We focus only on ML-DSA because that’s our main bet at the moment. If you’d like to understand what other algorithms look like, head over to the PQC Signature Zoo. […]”

Algorithm Public Key Size (bytes) Signature Size (bytes) 
RSA 2028 272 256 
RSA 3072 422 384 
RSA 4096 550 512 
ECDSA / P-256 65 72 
ECDSA / P-384 97 104 
ML-DSA-44 1,312 2,420 
ML-DSA-65 1,952 3,309 
ML-DSA-87 2,592 4,627 

(Table reproduced from the blogpost)